Influence of ion-plasma fibers treatment and silica nanoparticles on porous structure of Polikon anion-exchange membranes

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Abstract

The physicochemical properties and characteristics of the porous structure of “Polikon A” composite anion-exchange membranes, obtained by the method of polycondensation filling of polyester fiber, are studied. It is established that the total porosity, the specific surface area and specific moisture capacity of “Polikon A” composite membranes are comparable with these characteristics for the “Polikon K” membranes and are significantly higher than for the heterogeneous ion-exchange MA-40 membrane. It is found that the method of preparing silica nanoparticles, as well as preliminary ion-plasma treatment of fibers, significantly influence on the porous structure of the Polikon A membranes based on lavsan.

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About the authors

D. V. Terin

Yuri Gagarin State Technical University of Saratov; Saratov State University

Email: shkirskaya@mail.ru
Russian Federation, Politekhnicheskaya st., 77, Saratov, 410054; Astrakhanskaya st., 83, Saratov, 410012

М. М. Kardash

Yuri Gagarin State Technical University of Saratov

Email: shkirskaya@mail.ru
Russian Federation, Politekhnicheskaya st., 77, Saratov, 410054

N. А. Kononenko

Kuban State University

Email: shkirskaya@mail.ru
Russian Federation, Stavropolskaya st., 149, Krasnodar, 350040

S. А. Shkirskaya

Kuban State University

Author for correspondence.
Email: shkirskaya@mail.ru
Russian Federation, Stavropolskaya st., 149, Krasnodar, 350040

Yu. M. Volfkovich

Frumkin Institute of Physical Chemistry and Electrochemistry Russian Academy of Sciences

Email: shkirskaya@mail.ru
Russian Federation, Leninsky Prospekt, 31, building 4, Moscow, 119071

V. E. Sosenkin

Frumkin Institute of Physical Chemistry and Electrochemistry Russian Academy of Sciences

Email: shkirskaya@mail.ru
Russian Federation, Leninsky Prospekt, 31, building 4, Moscow, 119071

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Supplementary files

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2. Fig. 1. Integral (a, b) and differential (c, d) curves of water distribution by binding energies and effective pore radii in “Polycon A” membranes. The curve numbers in the figure correspond to the serial number of the sample in Table 1.

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3. Fig. 2. Integral (a) and differential (b) curves of the distribution of the surface of meso- and macropores by pore radii in “Polycon A” membranes. The curve numbers in the figure correspond to the serial number of the sample in Table 1.

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4. Fig. 3. Raman spectrum of polyester fibers of the “Lavsan” fabric before and after ion-plasma treatment.

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5. Fig. 4. Specific electrical conductivity of the “Polycon A” and MA-40 membranes in 0.1 M NaCl solution. The column numbers in the figure correspond to the serial number of the sample in Table 1.

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