Addition of alcohols to 4-methylene-1,3-dioxolanes

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The addition of alcohols to 2-methylene-1,4-dioxaspiro[4.5]decane under the conditions of CF3CO2H catalysis occurs with the selective formation of the corresponding alkoxy derivatives. The conditions that ensure the preparative isolation of target compounds in 63-94% yields are determined, and the relative activity of alcohols in the addition reaction at the exocyclic double bond of substrates is determined.

作者简介

S. Sokov

Ufa State Petroleum Technological University

Yu. Borisova

Ufa State Petroleum Technological University

Email: yulianna_borisova@mail.ru

G. Raskil'dina

Ufa State Petroleum Technological University

S. Zlotsky

Ufa State Petroleum Technological University

A. Golovanov

Ufa State Petroleum Technological University

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