On the Absence of Cyclic Structures in Branched Polystyrenes Synthesized by Living Three-Dimensional Radical Polymerization in the Medium of a Deteriorating Thermodynamic Quality Solvent

Мұқаба

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Тек жазылушылар үшін

Аннотация

Branched polystyrenes are synthesized by the radical copolymerization of styrene and divinylbenzene with reversible inhibition (in the presence of 2,2,6,6-tetramethylpiperidine-1-oxyl) under deteriorating thermodynamic quality of the solvent. The resulting polymers are studied by size-exclusion chromatography combined with static light scattering, ozonolysis, NMR spectroscopy, and differential scanning calorimetry. The branched polymers synthesized by living radical polymerization are characterized by lower intrinsic viscosity values than their linear analogs. Kuhn–Mark–Houwink parameters for these polymers in a tetrahydrofuran solution (а = 0.29) confirm the nonlinear architecture of macromolecules and a high content of pendant double bonds comparable in the order of magnitude with their theoretical content in the absence of the cyclization reaction indicate their branched structure. The glass transition temperature of the branched polystyrenes is 20–35°С lower than the glass transition temperature of the linear polystyrene.

Авторлар туралы

S. Kurochkin

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences; Bauman Moscow State Technical University

Email: oligo@icp.ac.ru
142432, Chernogolovka, Moscow oblast, Russia; 105005, Moscow, Russia

L. Makhonina

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences

Email: oligo@icp.ac.ru
142432, Chernogolovka, Moscow oblast, Russia

E. Perepelitsina

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences

Email: oligo@icp.ac.ru
142432, Chernogolovka, Moscow oblast, Russia

M. Bubnova

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences

Email: oligo@icp.ac.ru
142432, Chernogolovka, Moscow oblast, Russia

M. Berezin

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences

Email: oligo@icp.ac.ru
142432, Chernogolovka, Moscow oblast, Russia

V. Grachev

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences

Хат алмасуға жауапты Автор.
Email: oligo@icp.ac.ru
142432, Chernogolovka, Moscow oblast, Russia

Әдебиет тізімі

  1. Korolev G.V. // Russ. Chem. Rev. 2003. V. 72. № 3. P. 197.
  2. Korolev G.V., Bubnova M.L., Makhonina L.I., Bakova G.M. // Polymer Science A. 2005. V. 47. № 7. P. 653.
  3. Estrina G.A., Gur’eva L.L., Komarov B.A., Bogdanova L.M., Kurochkin S.A., Estrin Y.I. // Polymer Science B. 2018. V. 60. № 1. P. 1.
  4. Kurmaz S.V., Grubenko G.A., Knerelman E.I., Davydova G.I., Torbov V.I., Dremova N.N. // Mendeleev Commun. 2014. V. 24. № 2. P. 125.
  5. Kurmaz S.V., Fadeeva N.V., Gorshkova A.I., Kurochkin S.A., Knerelman E.I., Davydova G.I., Torbov V.I., Dremova N.N., Konev D.V., Kurmaz V.A., Ignatiev V.M., Emelyanova N.S. // Materials. 2021. V. 14. P. 6757.
  6. Vygodskii Y.S., Volkova T.V., Sakharova A.A., Sapozhnikov D.A., Nikiforova G.G., Matieva A.M. // Polymer Science A. 2006. V. 48. № 7. P. 683.
  7. Chesnokov S.A., Lenshina N.A., Arsenyev M.V., Kovylin R.S., Baten’kin M.A., Poddel’sky A.I., Abakumov G.A. // Appl. Organometal. Chem. 2017. V. 31. № 2. e3553.
  8. Novakov I.A., Vygodskii Y.S., Vaniev M.A., Volkova T.V., Lukyanichev V.V., Sidorenko N.V. // Polymer Science A. 2007. V. 49. № 4. P. 388.
  9. Liao W., Liao Q., Xiong Y., Li Z., Tang H. // J. Photochem. Photobiol. A. 2023. V. 435. 114297.
  10. Li Q., Tang L., Xia Y., Li B. // Macromol. Rapid Commun. 2013. V. 34. № 2. P. 185.
  11. Si C., Hu G., Jiang W., Sun P., Cao J., Ji R., Li A., Zhang Q. // Biomacromolecules. 2022. V. 23. № 10. P. 4327.
  12. Kurmaz S.V., Ivanova I.I., Fadeeva N.V., Perepelitsina E.O., Lapshina M.A., Balakina A.A., Terent’ev A.A. // Polymer Science A. 2022. V. 64. № 5. P. 434.
  13. Qiang R., Fanghong G., Chunlin L., Guangqun Z., Bibiao J., Chao L., Yunhui C. // Eur. Polym. J. 2006. V. 42. № 10. P. 2573.
  14. Li W., Yoon J.A., Zhong M., Matyjaszewski K. // Macromolecules. 2011. V. 44. № 9. P. 3270.
  15. Yang H.-J., Jiang B.-B., Huang W.-Y., Zhang D.-L., Kong L.-Z., Chen J.-H., Liu C.-L., Gong F.-H., Yu Q., Yang Y. // Macromolecules. 2009. V. 42. № 16. P. 5976.
  16. Kurochkin S.A., Silant’ev M.A., Perepelitsyna E.O., Grachev V.P. // Eur. Polym. J. 2014. V. 57. P. 202.
  17. Kurochkin S.A., Makhonina L.I., Vasil’ev S.G., Perepelitsina E.O., Zabrodin V.A., Bubnova M.L., Volkov V.I., Grachev V.P. // Polymer Science A. 2017. V. 59. № 5. P. 613.
  18. Liu G., Qui Q., An Z. // Polym. Chem. 2012. V. 3. № 2. P. 504.
  19. Shen W., Chang Y., Liu G., Wang H., Cao A., An Z. // Macromolecules. 2011. V. 44. № 8. P. 2524.
  20. van Ruymbeke E., Muliawan E.B., Vlassopoulos D., Gao H., Matyjaszewski K. // Eur. Polym. J. 2011. V. 47. № 4. P. 746.
  21. Shi X., Miao M., An Z. // Polym. Chem. 2013. V. 4. № 6. P. 1950.
  22. Tan J., Rao X., Wu X., Deng H., Yang J., Zeng Z. // Macromolecules. 2012. V. 45. № 21. P. 8790.
  23. Pan G., Zhang Y., Guo X., Li C., Zhang H. // Biosens. Bioelectron. 2010. V. 26. № 3. P. 976.
  24. Abe M., Kametani Y., Uemura T. // J. Am. Chem. Soc. 2023. V. 145. № 4. P. 2448.
  25. Korolev G.V., Kochneva I.S., Bakova G.M., Berezin M.P., Makhonina L.I. // Polymer Science A. 2002. V. 44. № 9. P. 936.
  26. Huang J., Wang W.-J., Li B.-G., Zhu S. // Macromol. Mater. Eng. 2013. V. 298. № 4. P. 391.
  27. Ercole F., Thissen H., Tsang K., Evans R.A., Forsythe J.S. // Macromolecules. 2012. V. 45. № 20. P. 8387.
  28. Park H.Y., Kloxin C.J., Fordney M.F., Bowman C.N. // Dental Mater. 2012. V. 28. № 8. P. 888.
  29. Yu Q., Zhou M., Ding Y., Jiang B., Zhu S. // Polymer. 2007. V. 48. № 24. P. 7058.
  30. Kurochkin S.A., Grachev V.P. // Polym. Sci. C. 2015. V. 57. № 1. P. 20.
  31. Wyatt P.J. // Anal. Chim. Acta. 1993. V. 272. № 1. P. 1.
  32. Kurochkin S.A. // Polymer Science B. 2010. V. 52. № 1–2. P. 109.
  33. Будтов В.П. Физическая химия растворов полимеров. СПб.: Химия, 1992.
  34. Polymer Handbook. 4 ed. / Ed. by J. Brandrup, E.H. Immergut, E.A. Grulke; ass. ed. by A. Abe, D.R. Bloch. New York; Chichester; Weinheim; Brisbane; Singapore; Toronto: Wiley, 1998.
  35. Zimm B.H., Stockmayer W.H. // J. Chem. Phys. 1949. V. 17. № 12. P. 1301.
  36. De Gennes P.-G. // Biopolymers. 1968. V. 6. № 5. P. 715.
  37. Everaers R., Grosberg A.Y., Rubinstein M., Rosa A. // Soft Matter. 2017. V. 13. P. 1223.
  38. Rosa A., Everaers R. // Phys. Rev. E. 2017. V. 95. № 1. 012117.
  39. Akabori K.-I., Atarashi H., Ozawa M., Nagamura T., Tanaka K. // Polymer. 2009. V. 50. № 20. P. 4868.
  40. Fox Jr., Thomas G., Flory P.J. // J. Appl. Phys. 1950. V. 21. № 21. P. 581.
  41. Bueche F. Physical Properties of Polymers. New York: Interscience, 1962.
  42. Привалко В.П. Молекулярное строение и свойства полимеров. Л.: Химия, 1986.
  43. Wooley K.L., Hawker C.J., Pochan J.M., Frechet J.M.J. // Macromolecules. 1993. V. 26. № 7. P. 1514.
  44. Аскадский А.А., Кондращенко В.И. Компьютерное материаловедение полимеров. М.: Научный мир, 1999. Т. 1.

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© С.А. Курочкин, Л.И. Махонина, Е.О. Перепелицина, М.Л. Бубнова, М.П. Березин, В.П. Грачев, 2023