Enthalpy of Interaction of Lithiated Nafion Membrane with Aqueous Solutions of Alcohols and Polar Aprotic Solvents
- 作者: Chernyuk S.D.1,2, Safronov A.P.1,3, Bushkova O.V.2
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隶属关系:
- Ural Federal University
- Institute of Solid State Chemistry of the Ural Branch of the Russian Academy of Sciences
- Institute of Electrophysics of the Ural Branch of the Russian Academy of Sciences
- 期: 卷 14, 编号 5 (2024)
- 页面: 378-386
- 栏目: Articles
- URL: https://kazanmedjournal.ru/2218-1172/article/view/677872
- DOI: https://doi.org/10.31857/S2218117224050047
- EDN: https://elibrary.ru/MYDSPU
- ID: 677872
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详细
The swelling degree of the lithiated form of the polyperfluorosulfone membrane Nafion (Li-Nafion) in alcohols (ethanol, 2-propanol), water-alcohol mixtures and in highly polar aprotic solvents (N, N-dimethylformamide (DMF), N-methyl-2-pyrrolidone (NMP)), as well as the thermodynamics of the interaction of the membrane with solvents were studied by the microcalorimetry method. It was shown that the values of the equilibrium swelling degree of the membrane correlate with the donor number of the solvent, as well as with the values of the enthalpy of swelling of the polymer. The swelling enthalpy of the Li-Nafion membrane in the solvents takes negative values, which indicates solvation of the polymer. The concentration dependences of the enthalpy of swelling and mixing of Li-Nafion in DMF and NMP were studied in more detail. Negative values of the swelling enthalpy of the polymer over the entire concentration range of solvents indicate good thermodynamic compatibility of the membrane with the solvent and the advantage of using these solvents to obtain Nafion dispersions due to their high solvating effect.
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作者简介
S. Chernyuk
Ural Federal University; Institute of Solid State Chemistry of the Ural Branch of the Russian Academy of Sciences
编辑信件的主要联系方式.
Email: univerekb@mail.ru
俄罗斯联邦, Ekaterinburg, 19, Mir St., 620020; Ekaterinburg, 91, Pervomayskaya St., 620049
A. Safronov
Ural Federal University; Institute of Electrophysics of the Ural Branch of the Russian Academy of Sciences
Email: univerekb@mail.ru
俄罗斯联邦, Ekaterinburg, 19, Mir St., 620020; Ekaterinburg, 106, Amundsen St., 620016
O. Bushkova
Institute of Solid State Chemistry of the Ural Branch of the Russian Academy of Sciences
Email: univerekb@mail.ru
俄罗斯联邦, Ekaterinburg, 91, Pervomayskaya St., 620049
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