Direct cross-dehydrogenative С–N-coupling of phenanthridine with 1H-benzotriazole

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Аннотация

An approach was developed for the direct C( sp 2)-H-functionalization of phenanthridine with a 1 H -benzotriazole residue, carried out in the presence of Selectfluor® reagent and leading to the formation of a C( sp 2)-N bond. The procedure described in this communication makes it possible to obtain α-(1 H -benzotriazol-1-yl)phenanthridine, which is a valuable synthon for further chemical transformations, in one step and using commercially available substrates and reagents.

Авторлар туралы

A. Akulov

Ural Federal University named after the first President of Russia B.N. Yeltsin

A. Pershin

Ural Federal University named after the first President of Russia B.N. Yeltsin

D. Kopchuk

Ural Federal University named after the first President of Russia B.N. Yeltsin;I.Ya. Postovsky Institute of Organic Synthesis, Russian Academy of Sciences, Ural Branch of the Russian Academy of Sciences

M. Varaksin

Ural Federal University named after the first President of Russia B.N. Yeltsin;I.Ya. Postovsky Institute of Organic Synthesis, Russian Academy of Sciences, Ural Branch of the Russian Academy of Sciences

G. Zyryanov

Ural Federal University named after the first President of Russia B.N. Yeltsin;I.Ya. Postovsky Institute of Organic Synthesis, Russian Academy of Sciences, Ural Branch of the Russian Academy of Sciences

Email: gvzyryanov@gmail.com

O. Chupakhin

Ural Federal University named after the first President of Russia B.N. Yeltsin;I.Ya. Postovsky Institute of Organic Synthesis, Russian Academy of Sciences, Ural Branch of the Russian Academy of Sciences

Әдебиет тізімі

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