


Vol 88, No 10 (2024)
Physics of magnetic fluids and composite materials based on them
Features of magnetic susceptibility of a ferrofluid with a non-magnetic filler
Abstract
We presented the results of an experimental study of the features of the magnetic susceptibility of a magnetic fluid with a non-magnetic filler. It is established that the dependence of magnetic susceptibility on the concentration of non-magnetic filler has features. The explanation of the detected effects is based on the assumption of the influence of surface forces on the relaxation processes of the magnetic moment of magnetic particles. It was also found that the dependences of the magnetic susceptibility of a magnetic fluid with a non-magnetic filler on the magnitude of the external magnetic field differ from similar dependences for a magnetic fluid without a filler.



Light absorption and light scattering in magnetic fluids with different aggregative stability
Abstract
The optical effects of dichroism, static scattering and light extinction of under the action of a magnetic field in magnetic fluids with an average particle size of 6.7 and 13.7 nm have been studied. Significant differences were found both in the magnitude of the effects and in their spectral behavior, which can be associated with the formation of aggregates in the sample with larger particles, which significantly change the optical properties of the system. The appearance of aggregates under the action of the field was confirmed by the method of dynamic light scattering.



Testing theoretical models on experimental data of magnetization of magnetopolymer composites
Abstract
Magnetic properties of magnetopolymer composite materials were studied. Monodisperse and bidisperse theoretical models considering interparticle dipole-dipole interactions were verified using experimental data. It was obtained that the bidisperse approximation well describe the experimental results for real polydisperse composites.



Influence of gyromagnetic effects on magnetization of magnetic liquids
Abstract
The influence of gyromagnetic effects on magnetization of a magnetic liquid that is regarded as a suspension of spherical rigidly magnetized particles in a uniform magnetic field is theoretically investigated. The expression for the magnetization of the suspension is obtained. The parameter that determines the influence of the gyromagnetic effects is estimated.



Electroconductivity of silicone-based elastomer filled with magnetically hard particles
Abstract
Silicone-based elastomer containing Nd-Fe-B-alloy particles garnished with a small portion of nickel grains has been studied for the capability to conduct alternating current. The observations suggest that the presence of nickel expands the variation range of the conductivity and magnetocapacitance in external magnetic fields. In addition, the composite demonstrates the memory of primary magnetizing manifesting itself as certain specific features of the hysteresis loops depending on the polarity of the external magnetic field.



Deformation of magnetic active elastomers in magnetic field
Abstract
Magnetoactive (aka magnetorheological) elastomer is a composite material consisting of an elastic matrix and magnetic filling substance. A study has been given to the magnetic field-induced deformation of the material. Influenced by non-homogeneous fields, samples of the elastomer have been noticed to exhibit elongations by hundreds of percent. When magnetized, the material filled with magnetically hard particles may exhibit field-induced deformation occurring in a complicated way. In a magnetic field, it reversibly gains a degree of roughness resulting in improved hydrophobicity. In addition, the composite increases in rigidity by tens of percent. Such magnetoactive elastomer may be considered a prospective material to find application in robotics and field-controlled damping units.



Magneto-optical effect in magnetic emulsions with deformable submicron droplets
Abstract
The effect of changes in the transparency of magnetic emulsions with deformable droplets of submicron size under the influence of a magnetic field has been studied. The influence of microdroplet concentration, orientation, and magnetic field strength on the amplitude of transparency changes was discovered. A comparison has been made of experimental data on the field dependence of the magneto-optical effect and the dependence on the angle of magnetic field orientation with calculations in the anomalous diffraction approximation. The possibility of estimating interfacial tension in magnetic emulsions based on studying the processes of relaxation of optical effects is discussed.



Controlled circuit with a capacitive cell based on magnetodielectric fluid
Abstract
We implemented a controlled oscillatory RLC circuit, in which a cell with a layer of magnetodielectric liquid is used as a capacitive element. The possibility of creating self-tuning inductive-capacitive elements based on a thin layer of magnetodielectric liquid is considered. It is shown that changing the properties of a magnetodielectric liquid in electric and magnetic fields makes it possible to create adjustable inductive-capacitive converters.



Magnetization features of small multi-core particles: theory and computer simulations
Abstract
We investigated the orientation texturing of magnetic moments of four magnetic nanoparticles fixed at the vertices of a regular tetrahedron and formed a separate polyhedral particle. Numerical calculations of the probability density of the magnetic moment orientation, the static magnetization and the initial magnetic susceptibility of a multi-core particle are obtained by the Monte-Carlo method.



Texturing of the magnetic nanoparticle easy axes during freezing of a magnetic suspension under the presence of an external field
Abstract
Solidification of a magnetic suspension under the presence of a magnetic field results in obtaining a ferrocomposite characterized by an orientational texture of the easy magnetization axes of nanoparticles. The characteristics of this texture are calculated under the condition when the interparticle magnetic dipole interaction is taken into account in the framework of the modified mean field theory. Theoretical predictions are confirmed by computer Monte Carlo simulation data.



Influence of the number of granules on the magnetization of multi-core particles
Abstract
We investigated the static magnetic response of the multi-core particles (MCP) with a different number of nanocores. The cases of the MCPs containing 7, 8, 32, 33, 123 and 136 granules are considered. Their position remains unchanged in the nodes of a regular cubic lattice, but the magnetic moments can freely rotate inside the cores. The magnetization of the MCPs is determined by computer simulation using the Monte Carlo method and theoretically.



Magnetization dynamics of a suspension of non-interacting magnetic particles under the presence of static uniform magnetic field
Abstract
The time process of the magnetization growth of a suspension of non-interacting magnetic particles is studied theoretically under the condition when this process starts developing switching on an external constant uniform magnetic field. It is found that the characteristic relaxation time of the process has the same value at the initial stage and at the final stage of reaching the equilibrium value of the magnetization and contains a minimum in the region of intermediate times.



Using magnetic composites to create controlled photon crystals
Abstract
A photonic crystal was created using a magnetic fluid–epoxy resin composite. The amplitude-frequency characteristics of the reflection coefficient of electromagnetic radiation in the microwave range from the resulting structure were experimentally studied. The possibility of using magnetic composites to create controlled photonic crystals has been demonstrated.



Microfluidics and ferrohydrodynamics of magnetic colloids
Features of the formation of a labyrinth structure in thin layers of magnetic fluids in a constant electric field
Abstract
We presented the results of studies of structural transformations in magnetic fluids when exposed to a constant electric field. The features of the formation of structural lattices in thin layers of colloids in an electric field directed perpendicular to the plane of the layer, as well as under the additional influence of a magnetic field, have been studied. New results were obtained related to the dependence of the threshold (critical) value of the electric field strength corresponding to the formation of a labyrinthine structure on the strength of an additionally applied magnetic field, layer thickness and temperature. The dependences of the formation time of the structure under study on temperature and the strength of an additionally applied magnetic field have been studied. A thermally induced effect of the appearance of a labyrinthine structure in a magnetic colloid in the subcritical region of the operating electric field strength under additional exposure to laser radiation has been discovered.



Study of electroconvection in magnetic fluids by dynamic light scattering
Abstract
Electroconvection in kerosene-based magnetic fluids was experimentally studied using the method of dynamic light scattering. A decrease in the relaxation time of the autocorrelation function was discovered at various voltages and interelectrode distances. Based on experimental data, the dependences of the maximum speed of chaotic electroconvective flows on the voltage on the electrodes and the distance between them were determined.



Formation and dynamics of droplets in a magnetic fluid in microchannels in an inhomogeneous magnetic field of ring magnet
Abstract
We studied the dynamics of non-magnetic droplets in magnetic liquids in microchannels with a “flow focusing” configuration under the action of an inhomogeneous magnetic field of an annular magnet. Two types of multiphase systems were studied: non-magnetic emulsions “oil in water”, “water in oil”, as well as “water in oil in water” and magnetic direct emulsions in which the magnetic liquid was used as a continuous phase. The dependences of the sizes of the generated non-magnetic inclusions on the flow rate of the continuous magnetic phase and the displacement of the magnetic field source relative to the dispersed phase supply connector horizontally along the channel axis are obtained.



On the problem of magneto-induced circulations in thrombosed channels
Abstract
A theoretical model and a method for its approximation analysis were developed to study circulation flows arising in a channel with a non-uniform alternating rotating magnetic field. This channel contains a non-magnetic fluid into which a cloud of ferrofluid is injected, the particles of which are distributed according to the Gaussian law along the channel. It is assumed that the right end of the channel is blocked to simulate a thrombosed vessel. The main goal of the study is to develop a scientific basis for increasing the efficiency of transport of thrombolytic drugs in thrombosed blood vessels using magnetic stimulation.



Heat transfer and vapor bubble formation during boiling of magnetic fluid on a single vapor formation center in an alternating magnetic field
Abstract
The frequency of vapor bubble formation and heat transfer during boiling of a magnetic fluid in a homogeneous alternating horizontal magnetic field are studied experimentally. Bubble formation occurs at a single vapor formation center. To measure the frequency of vapor bubble formation, an induction method based on the occurrence of induction current in the coil turns through which the vapor bubbles move is used. It is found that the specific heat flux and the frequency of vapor bubble formation depend significantly on the frequency of the magnetic field. The obtained results indicate the possibility of effective non-contact control of the boiling process of magnetic fluid, which may have practical application.



Shape of magnetic fluid surface near magnetic bodies in constant and alternating magnetic field
Abstract
The shape of the free surface of a magnetic fluid, which it takes in an external homogeneous magnetic field near solid magnetic bodies, is experimentally investigated. The shape of the magnetic fluid surface in the vicinity of bodies of different basic geometry: cylinder, ball, plate is studied. The pattern of the magnetic fluid surface under the influence of a stationary and alternating magnetic field is considered. It is shown that the shape of the surface essentially depends on the volume of the magnetic fluid, the geometry of the magnetic body and the magnitude of the magnetic field. The obtained results indicate the possibility of purposeful control of the shape of the free surface of magnetic fluid, which may have practical applications.



Dynamics of rising of an air bubble in a magnetic fluid shell in a magnetic field
Abstract
The process of rising of an air bubble enclosed in a magnetic fluid shell in an external homogeneous magnetic field directed horizontally is investigated experimentally. It is shown that the magnetic field acting on the magnetic fluid shell leads to a change in the shape of the bubble, which in turn is reflected in the quantitative characteristics of the rising process. Oscillations in the shape of the air bubble during the rising process were also found. The obtained results indicate the possibility of realizing the control of small gas volumes, which may have practical applications.



Dynamics of floating droplets of magnetic liquid in glycerin in a flat channel under the influence of a magnetic field
Abstract
The results of the study of the influence of the magnitude of the magnetic field strength and the concentration of the magnetic phase of the magnetic fluid (MF) on the elongation coefficient and the shape of the drop of MF floating in glycerin are presented. The dependences of the elongation coefficient of the ML droplet on the parameters of the magnetic fluids used and the strength of the magnetic field intensity are obtained.



Motion of a thin layer of magnetic fluid near a magnetizing body in a homogeneous magnetic field
Abstract
The flow of a thin layer of a magnetic fluid along a horizontal plane near an fixed magnetizable cylindrical body in an applied uniform vertical magnetic field were investigated theoretically and experimentally. The shapes of the surface of the magnetic fluid at different times were plotted. The influence of the applied field on the flow of the layer was studied.



Study of hydrogen-bonded complexes in aqueous solutions of acetylacetone using vibrational spectroscopy and ab initio calculations
Abstract
The Raman scattering and FT-IR absorption spectra of pure acetylacetone and its aqueous solutions at room temperature and atmospheric pressure were studied. The results of experiments and calculations show that with a decrease in the amount of acetylacetone in the solution, a red shift of the C=O stretching vibration band and a blue shift of the C-H stretching vibration band are observed. A potential energy distribution analysis was carried out for the monomeric molecule of the keto form of acetylacetone. The calculated and observed vibration frequencies are in good agreement. Calculations show that acetylacetone forms molecular clusters with water molecules in the form of C=O…H and C-H…O hydrogen bonds, which leads to a change in the shape of the spectral bands.



Study of the dynamics of model magnetic dispersed media under magnetic influence
Abstract
We considered a model medium of micron-sized magnetite particles and metal balls with a diameter of 1 mm in a viscous medium — glycerin. The processes of organization of this system in an external magnetic field as it increases are considered. The impact of shear vibrations on the processes of structure formation in the systems under study is also considered. The data obtained can serve as a basis for modeling the dynamics of disperse systems and expanding the understanding of their behavior and organization in magnetic fields and under mechanical influences.



Regularities and mechanisms of composition influence on magnetic and nonlinear electrical characteristics of La-Sr manganites with combined substitution for manganese
Abstract
The data are shown on magnetic properties and peculiarities of current-voltage characteristics of manganites with substitution of (Fe3+0.5Sc3+0.5), (Ni2+0.5Ge4+0.5), (Zn2+0.5Ge4+0.5), (Mg2+0.5Ge4+0.5) ions pairs for manganese in La-Sr system. The samples containing (Fe, Sc), (Ni, Ge) and (Zn, Ge) have S-shaped sections of negative differential resistance, and (Mg, Ge)-substituted manganite exhibits the property of voltage stabilization.


