Trinuclear Lutetium(III) Cyclopentadienyl Complex with the 2,2´-Bipyridine Dianion

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Abstract

The reaction of lutetium cyclopentadienyl anthracenide complex (C5H5)Lu(C14H10)(THF)2] with 1 equiv. of 2,2´-bipyridine in THF gives the trinuclear complex [{(η5-C5H5)Lu}3(μ₂-Bipy)₃] (I), containing a 2,2´-bipyridine dianion. The complex was isolated as a powder with the composition I·0.1(C14H10)·0.8(C7H8). The recrystallization from a toluene/hexane mixture resulted in the crystals of I·0.084(C14H10)·0.831(C7H8)· · 0.500(C6H14), which were studied by X-ray diffraction (monoclinic group P21/c; CCDC no. 2311508). Complex I has an unusual μ2-κ2N1,N1´:η4N1,C2,C2´,N1´-bridging coordination of the dianion.

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About the authors

D. A. Bardonov

Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences; Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences; National Research University, Higher School of Economics

Email: mminyaev@ioc.ac.ru
Russian Federation, Moscow; Moscow; Moscow

D. M. Roitershtein

Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences; Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Email: mminyaev@ioc.ac.ru
Russian Federation, Moscow; Moscow

D. I. Nasyrova

Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences; Moscow Institute of Physics and Technology

Email: mminyaev@ioc.ac.ru
Russian Federation, Moscow; Dolgoprudnyi, Moscow oblast

M. E. Minyaev

Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Author for correspondence.
Email: mminyaev@ioc.ac.ru
Russian Federation, Moscow

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Supplementary files

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2. Scheme 1. Synthesis of [{(η⁵-C₅H₅)Lu}₃(μ₂-Bipy)₃].

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3. Fig. 1. Molecular structure of {[(η⁵-C₅H₅)Lu]₃ [μ₂-κ²N¹,N¹´:η4N¹,C²,C²´,N¹´-Bipy]₃} (I): atoms ((a), hydrogen atoms are not shown) and non-coordinating organic molecules (b), the minor component of disorder, anthracene, is shown by open lines) in I · 0.084(C₁₄H₁₀) · 0.831(C₇H₈) · 0.500(C₆H₁₄) (p = 50%).

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