Influence of the Structure of Carbamoylmethylphosphine Oxides on the Extraction of Lanthanides(III) from Nitric Acid Solutions in the Presence of Dinonylnaphtalenesulfonic Acid

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Resumo

It was found that the extraction of lanthanides(III) from nitric acid solutions with solutions of carbamoylmethylphosphine oxides increases significantly in the presence of dinonylnaphthalene sulfonic acid. The stoichiometry of the extracted complexes was determined, and the influence of the composition of the aqueous phase, the nature of the organic solvent, and the structure of carbamoylmethylphosphine oxides on the efficiency of extraction of metal ions into the organic phase was considered.

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Sobre autores

A. Turanov

Yu. A. Osipyan Institute of Solid State Physics, Russian Academy of Sciences

Email: sharovaev@mail.ru
ORCID ID: 0000-0002-5064-191X
Rússia, Chernogolovka

V. Karandashev

Institute of Microelectronics Technology and High Purity Materials of the Russian Academy of Sciences

Email: sharovaev@mail.ru
ORCID ID: 0000-0003-0684-272X
Rússia, Chernogolovka

O. Artyushin

A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

Email: sharovaev@mail.ru
ORCID ID: 0000-0001-6333-5973
Rússia, Moscow

E. Sharova

A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

Autor responsável pela correspondência
Email: sharovaev@mail.ru
ORCID ID: 0000-0001-5428-596X
Rússia, Moscow

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2. Scheme 1

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3. Fig. 1. Extraction of Ln(III) from 3 mol/L HNO3 solutions by isomolar mixtures of 1a and dinonylnaphthalene sulfonic acid (DNNSA) in dichloroethane. [1a] + [DNNSA] = 0.05 mol/L

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4. Fig. 2. Dependence of Eu(III) distribution coefficients on HNO3 concentration in the aqueous phase during extraction with solutions of compound 1a (2), dinonylnaphthalene sulfonic acid (3) and a mixture of compound 1a and dinonylnaphthalene sulfonic acid (1) in dichloroethane. The concentration of compound 1a and dinonylnaphthalenesulfonic acid is 0.05 mol/L

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5. Fig. 3. Distribution coefficients of Ln(III) during extraction from 3 mol/L HNO3 solutions with 0.05 mol/L solutions of compounds 1a (1, 6), 1b (2, 7), 1c (4, 8), and 1g (3, 5) in dichloroethane (5-8) and dichloroethane containing 0.05 mol/L dinonylnaphthalene sulfonic acid (1-4)

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6. Fig. 4. Distribution coefficients of Ln(III) during extraction from 3 mol/L HNO3 solutions with solutions 1a and 2-8 in dichloroethane containing 0.02 mol/L dinonylnaphthalene sulfonic acid. The concentration of compounds 2-8 is 0.005 mol/l, compound 1a is 0.01 mol/l

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7. Fig. 5. Dependence of distribution coefficients of Eu (1, 6), Tb (2), Dy (3), Er (4), La (7), Tm (8) and Lu (5, 9) on the concentration of compounds 1a (6-9) and 2 (1-5) in dichloroethane containing 0.05 (6-9) and 0.02 mol/L (1-5) dinonylnaphthalene sulfonic acid, during extraction from 3 mol/L HNO3 solutions

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8. Fig. 6. Dependence of distribution coefficients of Eu (1), Tb (2), Dy (3), Er (4) and Lu (5) on the concentration of dinonylnaphthalene sulfonic acid (DNNSA) in dichloroethane containing 0.002 mol/L of compound 2 during extraction from solutions of 3 mol/L HNO3

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9. Fig. 7. Distribution coefficients of Ln(III) during extraction from 3 mol/L HNO3 solutions with 0.002 mol/L solutions of compound 2 in nitrobenzene (1), 1,2-dichloroethane (2), chloroform (3) and o-xylene (4) containing 0.01 mol/L dinonylnaphthalene sulfonic acid

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