Synthesis and Physicochemical Properties of Magnetic Fе3O4 Particles Doped with Gd(III)

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Resumo

Magnetic Fe3O4 nanoparticles were synthesized by alkaline precipitation of aqueous solutions of divalent and trivalent iron salts. Synthesis of Fe3−xGdxO4 nanoparticles (x = 0.05; 0.1) was performed by adding a calculated amount of Gd(NO3)3 6H2O to the initial solution of iron salt mixture. The phase composition and magnetic properties of the synthesized powders were investigated by X-ray phase analysis, Mössbauer spectroscopy on 57Fe isotope and magnetometry at temperatures T = 7, 20 and 300 K. The investigations confirmed the formation of nanoparticles of non-stehiometric Fe3−δO4 magnetite, as well as magnetite doped with Gd3+ ions. The correlation between the average diameter of nanoparticles of the initial Fe3−δO4 powder and doped Fe3−xGdxO4 powder and the salt used in the synthesis, as well as the concentration of Gd (x), respectively, was revealed.

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Sobre autores

E. Mitskevich

Belarusian State University

Autor responsável pela correspondência
Email: fcfvvv12@gmail.com
Belarus, 4, Nezavisimost Ave., Minsk, 220030

M. Degtyarik

Research Institute for Physical Chemical Problems of the Belarusian State University

Email: fcfvvv12@gmail.com
Belarus, 14, Leningradskaya St., Minsk, 220030

A. Kharchеnkо

Research Institute of Nuclear Problems of the Belarusian State University

Email: fcfvvv12@gmail.com
Belarus, 11, Bobruyskaya St., Minsk, 220030

М. Bushinsky

Practical Center of the National Academy of Sciences of Belarus for Materials Science

Email: fcfvvv12@gmail.com
Belarus, 19, P. Brovka St., Minsk, 220072

J. Fedotova

Research Institute of Nuclear Problems of the Belarusian State University

Email: fcfvvv12@gmail.com
Belarus, 11, Bobruyskaya St., Minsk, 220030

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2. Fig. 1. X-ray diffraction patterns of Fe3O4 (M1, M2) and Fe3-hGdxO4 samples at x = 0.05 (M3) and 0.10 (M4).

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3. Fig. 2. X-ray diffraction patterns (points) of Fe3O4 and Fe3-xGdxO4 samples at x = 0.05 and 0.1 in the angle range 38° < 2θ < 45° with approximation (solid lines); a - M1; b - M2; c - M3; d - M4.

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4. Fig. 3. Experimental (circles), approximation (red line) and noise (blue line) diffractograms of sample M1. The inset shows the experimental dependence of cos (θ) β on 4sin (θ) for the Williamson-Hall calculation.

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5. Fig. 4. Mössbauer spectra of samples M1-M4.

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6. Fig. 5. Magnetisation curves M (B) for all synthesised samples.

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7. Fig. 6. Example of M (B) curve approximation (experimental curve at T = 300 K (dots), envelope (red curve) and noise (blue curve)) by formula (4) for sample M1 (a) and enlarged fragment (b).

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