Di- and Octanuclear Iodoantimonates(III) with 1,2-Dimethylpyridinium and 3-Bromo-1-Ethyllpyridinium: Crystal Structure and Physico-Chemical Properties

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Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Тек жазылушылар үшін

Аннотация

By the reaction of SbI3 and iodides of the corresponding cations in organic solvents, two new antimony complexes were obtained — (3-Br-1-EtPy)3[Sb2I9] (1), (1,2-MePy)4[Sb8I28] (2). The features of the crystal structure of the compounds were determined by X-ray diffraction. The complexes are thermally stable up to at least 200°C and have a band gap of about 2.2 eV.

Толық мәтін

Рұқсат жабық

Авторлар туралы

I. Shentseva

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

Email: korobeynikov@niic.nsc.ru
Ресей, Novosibirsk

K. Tagiltsev

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University

Email: korobeynikov@niic.nsc.ru
Ресей, Novosibirsk; Novosibirsk

A. Usoltsev

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

Email: korobeynikov@niic.nsc.ru
Ресей, Novosibirsk

N. Korobeynikov

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University

Хат алмасуға жауапты Автор.
Email: korobeynikov@niic.nsc.ru
Ресей, Novosibirsk; Novosibirsk

V. Shayapov

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

Email: korobeynikov@niic.nsc.ru
Ресей, Novosibirsk

M. Sokolov

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

Email: korobeynikov@niic.nsc.ru
Ресей, Novosibirsk

S. Adonin

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences; Irkutsk Favorsky Institute of Chemistry of the Siberian Branch of the Russian Academy of Sciences

Email: korobeynikov@niic.nsc.ru
Ресей, Novosibirsk; Irkutsk

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2. Fig. 1. Non-covalent interactions (dotted line) in the crystal structure of compound 1. Hydrogen atoms are not shown

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3. Fig. 2. Structural type {α-M8I28} (a); anion structure of compound 2 (b). Antimony atoms are numbered

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4. Fig. 3. Contacts I···I (shown in dotted lines) in the anionic part of complex 2

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5. Fig. 4. Powder diffractograms of compounds 1 (a) and 2 (b): calculated from X-ray diffraction data (blue) and experimental (red)

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6. Fig. 5. TG, DTG, and DTA curves for junctions 1 (a) and 2 (b)

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7. Fig. 6. Diffuse reflection spectra of compounds 1 (a) and 2 (b)

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8. Supplementary 1
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9. Supplementary 2
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