Features of the synthesis of magnesium praseodymium hexaaluminate PrMgAl11O19 with a magnetoplumbite structure

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Resumo

RE magnesium hexaaluminates with magnetoplumbite structure are considered as potential candidates for thermal barrier coatings. However, the synthesis of single-phase samples is associated with certain difficulties. In this work, the features of PrMgAl11O19 preparation by reverse precipitation and citrate sol-gel synthesis are compared. Based on the results of thermal analysis of precursors, stepwise annealing of the samples was carried out, followed by X-ray phase analysis of the product. It is shown that the optimal condition for producing single-phase hexaaluminate PrMgAl11O19 is long-term annealing of tableted precursors obtained by the sol-gel method at a temperature of 1600°C. Thermodynamic assessment of possible reactions of praseodymium magnesium hexaaluminate formation from oxides confirmed the decomposition of PrMgAl11O19 at temperatures above 1700°C.

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Sobre autores

М. Ryumin

Kurnakov Institute of General and Inorganic Chemistry of RAS

Email: gagarin@igic.ras.ru
Rússia, Moscow, 119991

G. Nikiforova

Kurnakov Institute of General and Inorganic Chemistry of RAS

Email: gagarin@igic.ras.ru
Rússia, Moscow, 119991

P. Gagarin

Kurnakov Institute of General and Inorganic Chemistry of RAS

Autor responsável pela correspondência
Email: gagarin@igic.ras.ru
Rússia, Moscow, 119991

O. Kondrat’eva

Kurnakov Institute of General and Inorganic Chemistry of RAS

Email: gagarin@igic.ras.ru
Rússia, Moscow, 119991

K. Gavrcihev

Kurnakov Institute of General and Inorganic Chemistry of RAS

Email: gagarin@igic.ras.ru
Rússia, Moscow, 119991

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2. Fig. 1. Temperature dependences of heat flux and mass change of PrMgAl11O19 precursor obtained by the deposition method.

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3. Fig. 2. Diffractograms of PrMgAl11O19 precursor obtained by deposition method and annealed at 600 (1), 1000 (2), 1300 (3), 1400 (4), 1500 (5), 1600 (6) and 1700°C (7). P is PrAlO3 (perovskite), S is MgAl2O4 (spinel), C is a-Al2O3 (corundum), O is Pr6O11, and γ is γ-Al2O3. Unlabeled peaks refer to the PrMgAl11O19 phase with magnetoplumbite structure.

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4. Fig. 3. Results of thermal and thermogravimetric analysis of PrMgAl11O19 precursor obtained by sol-gel method.

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5. Fig. 4. Diffractograms of PrMgAl11O19 precursor prepared by sol-gel method and annealed at 1000 (1), 1500 (2), 1600 (3) and 1700°C (4). P is PrAlO3 (perovskite) and S is MgAl2O4 (spinel). Unlabeled peaks refer to the PrMgAl11O19 phase with magnetoplumbite structure.

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6. Fig. 5. Diffractogram of PrMgAl11O19.

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7. Fig. 6. Microphotograph of magnesium praseodymium hexaaluminate prepared by sol-gel synthesis method and annealed at 1600°C.

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8. Fig. 7. Temperature dependences of the Gibbs energy of the reactions of PrMgAl11O19 formation. 1-4 - numbers of reactions (see in the text).

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