Electrochromic Properties and Preparation of Thin V2O5 Films Using Heteroligand Complexes of Vanadyl
- Authors: Gorobtsov F.Y.1, Simonenko N.P.1, Simonenko Т.L.1, Simonenko E.P.1
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Affiliations:
- Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
- Issue: Vol 69, No 10 (2024)
- Pages: 1488-1496
- Section: НЕОРГАНИЧЕСКИЕ МАТЕРИАЛЫ И НАНОМАТЕРИАЛЫ
- URL: https://kazanmedjournal.ru/0044-457X/article/view/676644
- DOI: https://doi.org/10.31857/S0044457X24100152
- EDN: https://elibrary.ru/JHQAEC
- ID: 676644
Cite item
Abstract
Microstructural features, phase composition, and eletrochromic properties of V2O5 film formed by spin-coating using vanadyl alkoxoacetylacetonate as a precursor have been studied. The obtained material possesses a significant amount of V4+ ions, which is indicated both by the presence of the corresponding modes on the Raman spectra and the presence of the V7O16 phase. As a result, the material exhibits anodic electrochromism – it colors upon oxidation, changing color from pale blue to a much less transparent orange-yellow. The optical contrast can reach 30% at a wavelength of 400 nm, and the coloration efficiency is 65.26 cm2/C. The results of the study clearly demonstrate the promising application of materials based on V2O5, obtained using heteroligand hydrolytically active vanadyl complexes, as functional components of devices that provide a change in optical properties when an electrical voltage is applied.
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About the authors
F. Yu. Gorobtsov
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Author for correspondence.
Email: phigoros@gmail.com
Russian Federation, Moscow, 119991
N. P. Simonenko
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Email: phigoros@gmail.com
Russian Federation, Moscow, 119991
Т. L. Simonenko
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Email: phigoros@gmail.com
Russian Federation, Moscow, 119991
E. P. Simonenko
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Email: phigoros@gmail.com
Russian Federation, Moscow, 119991
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