SYNTHESIS OF Ti2AlC IN KBr MELT: EFFECT OF TEMPERATURE AND COMPONENT RATIO

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Abstract

MAX phases of various compositions have recently found increasing application due to their multilayer structure and properties that are characteristic of ceramic materials and metals. Therefore, the development of easily scalable methods for obtaining these compounds characterized by increased phase purity is of great importance. Within the framework of the work the influence on the composition and properties of such MAX phase, as Ti2AlC, conditions of its preparation with the use of protective melt of salts (on the example of KBr), in particular, ratios ofinitial reagents (n(Ti) : n(Al) : n(C)), temperature and duration of heat treatment has been studied. It was found that at the temperature 1100∘C the highest yield of Ti2AlC (94.4%) can be obtained in the case of using the molar ratio n(Ti) : n(Al) : n(C) = 2 : 1.1 : 0.9. It is shown that the use of synthesis temperatures from 900 to 1100∘C changes the content of the target MAX phase insignificantly(from 94 to 96%), the maximum content of Ti2AlC was found in the case of obtaining a sampleat the temperature 1000∘C. The influence of synthesis temperature (900, 1100 and 1200∘C) on microstructure, thermal behavior in air current and the value of electron work function was alsostudied.

About the authors

E. P. Simonenko

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: ep_simonenko@mail.ru
Moscow, Russia

I. A. Nagornov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Moscow, Russia

A. S. Mokrushin

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Moscow, Russia

V. M. Sapronova

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences; Mendeleev Russian University of Chemical Technology, Mendeleev Russian Chemical and Technological University

Moscow, Russia; Moscow, Russia

Ph. Yu. Gorobtsov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Moscow, Russia

N. P. Simonenko

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Moscow, Russia

N. T. Kuznetsov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Moscow, Russia

References

  1. Simonenko E.P., Simonenko N.P., Nagornov I.A. et al. // Russ. J. Inorg. Chem. 2022. V. 67.№5. P. 705. https://doi.org/ 10.1134/S0036023622050187
  2. Haftani M., Saeedi Heydari M., Baharvandi H.R. et al. // Int. J. Refract. Met. Hard Mater. 2016. V. 61. P. 51. https://doi.org/ 10.1016/j.ijrmhm.2016.07.006
  3. Tallman D.J., Anasori B., Barsoum M.W. // Mater. Res. Lett. 2013. V. 1.№3. P. 115. https://doi.org/ 10.1080/21663831.2013.806364
  4. Elsenberg A., Busato M., Gartner F. et al. // J. Therm. Spray Technol. 2021. V. 30.№3. P. 617. https://doi.org/ 10.1007/s11666-020-01110-w
  5. Poulou A., Mellan T.A., Finnis M.W. // Phys. Rev. Mater. 2021. V. 5.№3. P. 033608. https://doi.org/10.1103/PhysRevMaterials.5.033608
  6. Aydinyan S. // Ceram. Int. 2024. V. 50.№7. P. 12263. https://doi.org/10.1016/j.ceramint.2024.01.130
  7. Li Z., Zhang Y., Wang K. et al. // Corros. Sci. 2024. V. 228. P. 111820. https://doi.org/10.1016/j.corsci.2024.111820
  8. Liu P.,Wang Z., Ye F. et al. // Composites Part B: Eng. 2024. V. 273. P. 111259. https://doi.org/10.1016/j.compositesb.2024.111259
  9. Lee H., Kim S.Y., Lee Y. et al. // J. Am. Ceram. Soc. 2023. V. 106.№12. P. 7230. https://doi.org/10.1111/jace.19217
  10. Simonenko T.L., Simonenko N.P., Gorobtsov P.Y. et al. // Materials (Basel). 2023. V. 16.№18. P. 6133. https://doi.org/10.3390/ma16186133
  11. Bharti B., Kumar Y., Gupta M. et al. // ECS Trans. 2022. V. 107.№1. P. 1751. https://doi.org/10.1149/10701.1751ecst
  12. Aslam M.K., Xu M. // Nanoscale. 2020. V. 12.№30. P. 15993. https://doi.org/10.1039/D0NR04111D
  13. Cichero M.C., Zimnoch Dos Santos J.H. // Mater. Res. Found. 2019. V. 51. P. 1. https://doi.org/10.21741/9781644900253-1
  14. Simonenko E.P., Simonenko N.P., Mokrushin A.S. et al. // Nanomaterials. 2023. V. 13.№5. P. 850. https://doi.org/10.3390/nano13050850
  15. Simonenko E.P., Nagornov I.A., Mokrushin A.S. et al. // Materials (Basel). 2023. V. 16.№13. P. 4506. https://doi.org/10.3390/ma16134506
  16. Simonenko E.P., Simonenko N.P., Nagornov I.A. et al. // Russ. J. Inorg. Chem. 2022. V. 67. № 11. P. 1850. https://doi.org/10.1134/ S0036023622601222
  17. Ganesh P.-S., Kim S.-Y. // J. Ind. Eng. Chem. 2022. V. 109. P. 52. https://doi.org/10.1016/j.jiec.2022.02.006
  18. Sivasankarapillai V.S., Sharma T.S.K., Hwa K.-Y. et al. // ES Energy Environ. 2022. V. 15. P. 4. https://doi.org/10.30919/esee8c618
  19. Alwarappan S., Nesakumar N., Sun D. et al. // Biosens. Bioelectron. 2022. V. 205. P. 113943. https://doi.org/10.1016/j.bios.2021.113943
  20. Shah N., Wang X., Tian J. // Mater. Chem. Front. 2023. V. 7.№19. P. 4184. https://doi.org/10.1039/D3QM00216K
  21. Li K., Zhang S., Li Y. et al. // Chinese J. Catal. 2021. V. 42.№1. P. 3. https://doi.org/10.1016/S1872-2067(20)63630-0
  22. Xie X., Zhang N. // Adv. Funct. Mater. 2020. V. 30. №36. P. 2002528. https://doi.org/10.1002/adfm.202002528
  23. Liu Z., Sun C., Xu M. et al. // Mater. Lett. 2024.V. 365. P. 136437. https://doi.org/10.1016/j.matlet.2024.136437
  24. Wang W., Xu J., Zuo J. et al. // Acta Metall. Sin. (English Lett). 2024. V. 37.№4. P. 739. https://doi.org/10.1007/s40195-023-01647-z
  25. Perevislov S.N., Sokolova T.V., Stolyarova V.L. // Mater. Chem. Phys. 2021. V. 267. P. 124625. https://doi.org/10.1016/j.matchemphys.2021.124625
  26. Hoffman E.N., Vinson D.W., Sindelar R.L. et al. // Nucl. Eng. Des. 2012. V. 244. P. 17. https://doi.org/10.1016/j.nucengdes.2011.12.009
  27. Qiu B.,Wang J., Deng Y. et al. // Nucl. Eng. Technol. 2020. V. 52.№1. P. 1. https://doi.org/10.1016/j.net.2019.07.030
  28. Azina C., Badie S., Litnovsky A. et al. // Sol. Energy Mater. Sol. Cells. 2023. V. 259. P. 112433. https://doi.org/10.1016/j.solmat.2023.112433
  29. Ma H.-B., Xue J.-X., Zhai J.-H. et al. // Ceram. Int. 2020. V. 46.№9. P. 14269. https://doi.org/10.1016/j.ceramint.2020.02.155
  30. Fitriani P., Yoon D.-H. // Ceram. Int. 2018. V. 44. №18. P. 22943. https://doi.org/10.1016/j.ceramint.2018.09.090
  31. Fitriani P., Septiadi A., Hyuk J.D. et al. // J. Eur. Ceram. Soc. 2018. V. 38.№10. P. 3433. https://doi.org/10.1016/j.jeurceramsoc.2018.04.006
  32. Septiadi A., Fitriani P., Sharma A.S. et al. // J. Korean Ceram. Soc. 2017. V. 54.№4. P. 340. https://doi.org/10.4191/kcers.2017.54.4.08
  33. Jimenez C., Mergia K., Lagos M. et al. // J. Eur. Ceram. Soc. 2016. V. 36.№3. P. 443. https://doi.org/10.1016/j.jeurceramsoc.2015.09.038
  34. Katoh Y., Snead L.L., Cheng T. et al. // J. Nucl. Mater. 2014. V. 448.№1–3. P. 497. https://doi.org/10.1016/j.jnucmat.2013.10.002
  35. Wu J., Yan J., Peng H. et al. // J. Eur. Ceram. Soc. 2024. V. 44.№6. P. 3777. https://doi.org/10.1016/j.jeurceramsoc.2023.12.097
  36. Chen W., Chen J., Zhu M. et al. // J. Eur. Ceram. Soc. 2021. V. 41.№13. P. 6248. https://doi.org/10.1016/j.jeurceramsoc.2021.06.037
  37. Badie S., Dash A., Sohn Y.J. et al. // J. Am. Ceram. Soc. 2021. V. 104.№4. P. 1669. https://doi.org/10.1111/jace.17582
  38. Cai L., Huang Z., Hu W. et al. // Int. J. Appl. Ceram. Technol. 2018. V. 15.№5. P. 1212. https://doi.org/ 10.1111/ijac.12902
  39. Naik Parrikar P., Benitez R., Gao H. et al. // Exp. Mech. 2017. V. 57.№5. P. 675. https://doi.org/10.1007/s11340-017-0264-4
  40. Bei G., Pedimonte B., Fey T. et al. // J. Am. Ceram. Soc. 2013. V. 96.№5. P. 1359. https://doi.org/10.1111/jace.12358
  41. He G., Zhang Y., Yao P. et al. // J. Mater. Sci. Technol. 2023. V. 137. P. 91. https://doi.org/10.1016/j.jmst.2022.07.037
  42. Rangaraj L., Kashimatt V., Pooja et al. // Int. J. Appl. Ceram. Technol. 2022. https://doi.org/10.1111/ijac.14064
  43. Podhurska V.Y., Ostash O.P., Vasyliv B.D. et al. // Wear Resistance of Ti–Al–C MAX Phases-Based Materials for Pantographs Inserts of Electric Vehicles. 2021. Р. 607. https://doi.org/10.1007/978-3-030-51905-6_42
  44. Liu Z., Yang J., Qian Y. et al. // Ceram. Int. 2020. V. 46.№14. P. 22854. https://doi.org/10.1016/j.ceramint.2020.06.055
  45. Magnus C., Cooper D., Sharp J. et al. // Wear. 2019. V. 438–439. P. 203013. https://doi.org/10.1016/j.wear.2019.203013
  46. Hu L., Kothalkar A., Proust G. et al. // J. Alloys Compd. 2014. V. 610. P. 635. https://doi.org/10.1016/j.jallcom.2014.04.224
  47. Chen Y.L., Zhu X.Y., Lu P.J. et al. // Appl. Mech. Mater. 2014. V. 543–547. P. 3869. https://doi.org/10.4028/www.scientific.net/AMM.543547.3869
  48. Liu X., Jia Q., Zhang S. et al. // Int. Mater. Rev. 2024. V. 69.№2. P. 107. https://doi.org/10.1177/09506608231219864
  49. Galvin T., Hyatt N.C., Rainforth W.M. et al. // J. Eur. Ceram. Soc. 2018. V. 38.№14. P. 4585. https://doi.org/10.1016/j.jeurceramsoc.2018.06.034
  50. Dash A., Va.en R., Guillon O. et al. // Nat. Mater. 2019. V. 18.№5. P. 465. https://doi.org/10.1038/s41563-019-0328-1
  51. Luo W., Liu Y., Wang C. et al. // J. Mater. Chem. C. 2021. V. 9.№24. P. 7697. https://doi.org/10.1039/D1TC01338F
  52. Nadimi H., Soltanieh M., Sarpoolaky H. // Ceram. Int. 2022. V. 48.№7. P. 9024. https://doi.org/10.1016/j.ceramint.2021.12.084
  53. Liu Z., Xu J., Xi X. et al. // Ceram. Int. 2023. V. 49. №1. P. 168. https://doi.org/10.1016/j.ceramint.2022.08.325
  54. Zhong Y., Liu Y., Jin N. et al. // J. Am. Ceram. Soc. 2023. V. 106.№9. P. 5567.https://doi.org/10.1111/jace.19178
  55. Zhang Z., Zhou Y., Wu S. et al. // Ceram. Int. 2023. V. 49.№22. P. 36942. https://doi.org/10.1016/j.ceramint.2023.09.025
  56. Tan Y., Xia Y., Teng Z. et al. // J. Eur. Ceram. Soc. 2021. V. 41.№8. P. 4658. https://doi.org/10.1016/j.jeurceramsoc.2021.03.027
  57. Simonenko E.P., Nagornov I.A., Mokrushin A.S. et al. // Micromachines. 2023. V. 14.№4. P. 725. https://doi.org/10.3390/mi14040725
  58. Liu A., Yang Q., Ren X. et al. // Ceram. Int. 2020. V. 46.№5. P. 6934. https://doi.org/10.1016/j.ceramint.2019.11.008
  59. Roy C., Banerjee P., Bhattacharyya S. // J. Eur. Ceram. Soc. 2020. V. 40.№3. P. 923. https://doi.org/10.1016/j.jeurceramsoc.2019.10.020
  60. Roy C., Banerjee P., Mondal S. et al. // Mater. Today Chem. 2022. V. 26. P. 101160. https://doi.org/10.1016/j.mtchem.2022.101160
  61. Симоненко Е.П., Мокрушин А.С., Нагорнов И.А. и др. // Журн. неорган. химии. 2024. № 9.

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