“DIIMINE-NiII-CATECHOLATE” CHROMOPHORES BASED ON PHENANTHROLINE- TYPE LIGAND SYSTEMS: MOLECULAR STRUCTURE, “LIGAND-TO-LIGAND” CHARGE TRANSFER, AND THERMAL BEHAVIOR

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A series of chromophoric complexes NiII(3,6-Cat)(Phen) (1), NiII(3,6-Cat)(DPQ) (2) and NiII(3,6-Cat)(DPPZ) (3) (where 3,6-Cat is 3,6-di-tert-butyl-catecholate dianion) has been synthesized using 1,10-phenanthroline (Phen), dipyrido[3,2-d:2’,3’-f]quinoxaline (DPQ), and dipyrido[3,2-a:2’,3’-c]phenazine (DPPZ). Chromophores 1-3 have a slightly distorted planarstructure of the coordination environment and undergo photoinduced ligand-to-ligandintramolecular charge transfer (HOMOdonor →LUMOacсeptor), thus demonstrating stronglight absorption in visible and near-IR regions. Complexes 1-3are characterized by high thermostability and complete transition to the vapor phase under reduced pressure conditions. Compound 1has high volatility, which makes it a suitable candidate for further testing in thefabrication of optoelectronic devices by “evaporation-deposition” technology.

作者简介

K. Pashanova

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences

Email: pashanova@iomc.ras.ru
Nizhny Novgorod, Russia

I. Yakushev

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Moscow, Russia

N. Lazarev

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences

Nizhny Novgorod, Russia

A. Zolotukhin

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences

Nizhny Novgorod, Russia

T. Kovylina

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences

Nizhny Novgorod, Russia

A. Klimashevskaya

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences

Nizhny Novgorod, Russia

М. Arsenyev

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences

Nizhny Novgorod, Russia

O. Sulimova

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Moscow, Russia

P. Dorovatovskii

National Research Centre “Kurchatov Institute”

Moscow, Russia

A. Piskunov

Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences

Nizhny Novgorod, Russia

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