Synthesis, Ion-Exchange and Photocatalytic Properties of Layered Perovskite-Like CsBa2Nb3O10 Niobate: Comparative Analysis with Related AA′2Nb3O10 Dion-Jacobson Phases (A = K, Rb, Cs; A′ = Ca, Sr, Pb)

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Abstract

Layered perovskite-like niobate CsBa2Nb3O10 has been synthesized in a pure single-phase state for the first time using both nitrates and carbonates of cesium and barium. Unlike its Ca-, Sr- and Pb-containing analogues, the niobate obtained was shown not to undergo substitution of interlayer alkali cations with protons (protonation) upon acid treatments under various conditions. A potential reason for its chemical inactivity may consist in partial disordering of cesium and barium cations between the interlayer space and perovskite slab, hindering the interlayer ion exchange. Optical bandgap energy of CsBa2Nb3O10, being equal to 2.8 eV, potentially allows using visible light (λ < 443 nm) for driving photocatalytic reactions. However, the photocatalytic potential of this niobate towards hydrogen production remains untapped since the activity of the interlayer space in protonation and hydration reactions, as shown earlier, is a fundamentally important factor determining the photocatalytic performance of ion-exchangeable layered perovskite-like oxides.

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About the authors

S. A. Kurnosenko

Saint Petersburg State University

Email: irina.zvereva@spbu.ru
Russian Federation, Saint Petersburg

O. I. Silyukov

Saint Petersburg State University

Email: irina.zvereva@spbu.ru
Russian Federation, Saint Petersburg

I. A. Rodionov

Saint Petersburg State University

Email: irina.zvereva@spbu.ru
Russian Federation, Saint Petersburg

Ya. P. Biryukov

Institute of Silicate Chemistry of the Russian Academy of Sciences

Email: irina.zvereva@spbu.ru
Russian Federation, Saint Petersburg

A. A. Burov

Saint Petersburg State University

Email: irina.zvereva@spbu.ru
Russian Federation, Saint Petersburg

I. A. Zvereva

Saint Petersburg State University

Author for correspondence.
Email: irina.zvereva@spbu.ru
Russian Federation, Saint Petersburg

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Supplementary files

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2. Fig. 1. X-ray diffractograms of CBN3 samples before and after their treatment with 12 M HCl and water. Impurity phases are marked with an asterisk.

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3. Fig. 2. Raman spectra of CBN3 before and after treatment with 12 M HCl and water. The range 1500-4000 cm-1 has been increased by a factor of 20.

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4. Fig. 3. TG curves of CBN3 before and after treatment with 12 M HCl and water.

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5. Fig. 4. Diffuse reflectance spectra (a) and corresponding Kubelka-Munk plots (b) for CBN3 before and after treatment with 12 M HCl.

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6. Fig. 5. Kinetic curves of photocatalytic hydrogen evolution from 1 mol% aqueous methanol under DRT-125 lamp irradiation using initial and acid-treated CBN3 samples without additional modification (a) and with 1% Pt as a co-catalyst (b).

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