Estimated hansen solubility parameters of low-dimensional vanadium, niobium and tantalum dichalcogenides
- Авторлар: Nikonov К.S.1, Menshikova Т.К.1, Brekhovskikh М.N.1
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Мекемелер:
- Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
- Шығарылым: Том 69, № 5 (2024)
- Беттер: 672-680
- Бөлім: СИНТЕЗ И СВОЙСТВА НЕОРГАНИЧЕСКИХ СОЕДИНЕНИЙ
- URL: https://kazanmedjournal.ru/0044-457X/article/view/666525
- DOI: https://doi.org/10.31857/S0044457X24050038
- EDN: https://elibrary.ru/YFMQDC
- ID: 666525
Дәйексөз келтіру
Аннотация
Low-dimensional flakes of transitional metal dichalcogenides TaX2 (X = S, Se, Te), VSe2 and NbSe2 were acquired using liquid-phase exfoliation process. Hansen solubility parameters of those dispersions were estimated by measuring extinction in a number of various liquid environments. Amount of low-dimensional particles of dichalcogenides in a sample increases with decrease of Hansen distance between dichalcogenide and exfoliation medium. We propose a method to qualitatively estimate the impact exfoliation medium has on the size of forming particles and demonstrate how decrease of the absolute value of δpolar and δhydrogen in examined systems leads to decrease in size of forming flakes.
Авторлар туралы
К. Nikonov
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Хат алмасуға жауапты Автор.
Email: nikonovk.s@yandex.ru
Ресей, Moscow
Т. Menshikova
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Email: nikonovk.s@yandex.ru
Ресей, Moscow
М. Brekhovskikh
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Email: nikonovk.s@yandex.ru
Ресей, Moscow
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