Synthesis of C-mercuro derivatives of ortho-carborane. Crystal structure of bis(2-phenyl-ortho-carboran-1-yl)mercury

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Many carborane derivatives, first synthesized during the rapid development of this field of chemistry in the 60s of the last century, remained completely uncharacterized by modern spectral and structural methods. In this work, a series of C-mercuro derivatives of ortho-carborane 1-PhHg-2-Ph-1,2-C2B10H10 and (2-R-1,2-C2B10H10)2Hg (R = H, Me, Ph) were newly synthesized and characterized by NMR spectroscopy. The molecular crystal structure of bis(2-phenyl-ortho-carboran-1-yl)mercury was determined by single crystal X-ray diffraction.

作者简介

S. Anufriev

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

Email: sivaev@ineos.ac.ru
俄罗斯联邦, Moscow

S. Timofeev

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

Email: sivaev@ineos.ac.ru
俄罗斯联邦, Moscow

D. Nasyrova

Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences; Moscow Institute of Physics and Technology

Email: sivaev@ineos.ac.ru
俄罗斯联邦, Moscow; Dolgoprudny

I. Sivaev

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences; Plekhanov Russian University of Economics

编辑信件的主要联系方式.
Email: sivaev@ineos.ac.ru
俄罗斯联邦, Moscow; Moscow

V. Bregadze

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

Email: sivaev@ineos.ac.ru
俄罗斯联邦, Moscow

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Посвящается 125-летию со дня рождения академика А.Н. Несмеянова и 70-летию основания Института элементоорганических соединений Российской академии наук.


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