Copper(II) complexes with mono- and doubly reduced forms of 3,5-di-tert-octyl-o-benzoquinone

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Copper(II) complexes on the basis of 3,5-di-tert-octyl-o-benzoquinone (3,5-tOc-Q) have been synthesised. Derivatives of the composition: (3,5-tOc-SQ)2Cu (I), (3,5-tOc-Cat)Cu(Phen) (II), (3,5-tOc-Cat)Cu(DPQ) (III) and (3,5-tOc-Cat)Cu(DPPZ) (IV), where 3,5-tOc-SQ is the anion radical of 3,5-di-tert-octyl-o-benzoquinone, 3,5-tOc-Cat is the dianion of 3,5-di-tert-octyl-o-benzoquinone, Phen is phenanthroline, DPQ is dipyrido[3,2-d: 2′,3′-f]quinoxaline, DPPZ — dipyrido[3,2-a:2′,3′-c]phenazine. The molecular and crystal structures of complexes I and II were established by X-ray diffraction. The spectral characteristics of the synthesised copper(II) derivatives have been investigated by electronic absorption spectroscopy. Crystallographic data for compounds I and II have been deposited in the Cambridge Structural Data Bank (No. 2291614 for I and No. 2279045 for II).

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Sobre autores

O. Trofimova

Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences

Autor responsável pela correspondência
Email: olesya@iomc.ras.ru
Rússia, Nizhny Novgorod, 603950

A. Maleeva

Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences

Email: olesya@iomc.ras.ru
Rússia, Nizhny Novgorod, 603950

M. Arseniev

Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences

Email: olesya@iomc.ras.ru
Rússia, Nizhny Novgorod, 603950

T. Kocherova

Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences

Email: olesya@iomc.ras.ru
Rússia, Nizhny Novgorod, 603950

A. Cherkasov

Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences

Email: olesya@iomc.ras.ru
Rússia, Nizhny Novgorod, 603950

I. Yakushev

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: olesya@iomc.ras.ru
Rússia, Moscow, 119991

P. Dorovatovski

National Research Center “Kurchatov Institute”

Email: olesya@iomc.ras.ru
Rússia, Moscow, 123182

A. Piskunov

Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences

Email: olesya@iomc.ras.ru
Rússia, Nizhny Novgorod, 603950

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2. Fig. 1. The molecular structure of complex I. Thermal ellipsoids are given with a 50% probability. Hydrogen atoms are not shown.

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3. Fig. 2. The molecular structure of complex II. Thermal ellipsoids are given with a 50% probability. Hydrogen atoms are not shown.

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4. Fig. 3. Intermolecular contacts in II.

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5. Fig. 4. Electronic absorption spectra of solutions of complexes I, II, IV (C = 6.3 × 10-4 mol/l) and III (C = 6.4 × 10-4 mol/l).

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6. Scheme 1.

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7. Scheme 2.

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