Mechanochemical Synthesis of closo-Decaborate Anion Derivatives with Pendant Functional Groups

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A new method for the preparation of derivatives of the closo-decaborate anion with pendant functional groups has been developed, which includes the reaction of 1,4-dioxane, tetrahydropyran, and tetrahydrofuran derivatives of the [B10H10]2– anion with C-, O-, S-, and F-nucleophilic reagents (potassium cyanide, potassium hydroxide, sodium acetate, potassium hydrosulfide, potassium thiocyanate, sodium thiosulfate, and potassium fluoride) under mechanochemical conditions. It has been shown that these reactions proceed through the opening of exopolyhedral substituents of the oxonium type and lead to the formation of closo-decaborates with the corresponding С-, O-, S-, and Hal-functional groups. The developed method makes it possible to synthesize derivatives of the [B10H10]2– anion with pendant groups of various structures in a short time and without using aprotic polar solvents, which greatly facilitates the process of product isolation. The resulting closo-decaborates due to the presence of donor centers of various types can be used as polydentate ligands to obtain complex compounds of d-elements. In addition, the synthesized compounds can be used as a platform for further functionalization due to the reactivity of the attached pendant groups. The obtained derivatives of the [B10H10]2– anion have been studied by elemental analysis, IR, 11B, 13C, 1H NMR spectroscopy, and ESI mass spectrometry. The structure of Cs2[B10H9O(CH2)2O(CH2)2SCN] compound has been determined using X-ray diffraction.

Sobre autores

E. Matveev

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences; Lomonosov Institute of Fine Chemical Technologies, MIREA—Russian Technological University

Email: cat1983@yandex.ru
119991, Moscow, Russia; 119571, Moscow, Russia

A. Kubasov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: cat1983@yandex.ru
119991, Moscow, Russia

A. Nichugovskii

Lomonosov Institute of Fine Chemical Technologies, MIREA—Russian Technological University

Email: cat1983@yandex.ru
119571, Moscow, Russia

V. Avdeeva

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: cat1983@yandex.ru
119991, Moscow, Russia

K. Zhizhin

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences; Lomonosov Institute of Fine Chemical Technologies, MIREA—Russian Technological University

Email: cat1983@yandex.ru
119991, Moscow, Russia; 119571, Moscow, Russia

N. Kuznetsov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Autor responsável pela correspondência
Email: avdeeva.varvara@mail.ru
119571, Moscow, Russia

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Declaração de direitos autorais © Е.Ю. Матвеев, А.С. Кубасов, А.И. Ничуговский, В.В. Авдеева, К.Ю. Жижин, Н.Т. Кузнецов, 2023