Extraction of Uranyl Tricarbonate Complex by Clay Materials from Aqueous Solutions

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Abstract

The processes of extraction of the tricarbonate complex of uranyl [UO2(CO3)3]4– from aqueous solutions on clay powders from kaolin clays of the Kampanovskoye deposit and from bentonite clays of the 10th Khutor and Dinozavrovoe deposits, as well as their mixtures, were investigated. The studies were carried out with clay powders, both untreated and treated with water, solutions of 0.5 mol/l Na2CO3 and NaNO3, and 2 mol/l solutions of NaOH. It has been shown that the [UO2(CO3)3]4- complex is not sorbed on clay materials from aqueous solutions under static conditions. It has been established that filtration of an aqueous solution of [UO2(CO3)3]4- through columns with clay mixtures allows one to extract up to 87% of uranium from the amount passed through the column

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About the authors

E. P. Krasavina

Frimkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: kulyukhin@ipc.rssi.ru
Russian Federation, Leninskii pr. 31, korp. 4, Moscow, 119071

K. V. Martynov

Frimkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: kulyukhin@ipc.rssi.ru
Russian Federation, Leninskii pr. 31, korp. 4, Moscow, 119071

K. G. Arzumanova

Frimkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: kulyukhin@ipc.rssi.ru
Russian Federation, Leninskii pr. 31, korp. 4, Moscow, 119071

A. A. Bessonov

Frimkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: kulyukhin@ipc.rssi.ru
Russian Federation, Leninskii pr. 31, korp. 4, Moscow, 119071

A. V. Gordeev

Frimkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: kulyukhin@ipc.rssi.ru
Russian Federation, Leninskii pr. 31, korp. 4, Moscow, 119071

A. Y. Bomchuk

Frimkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: kulyukhin@ipc.rssi.ru
Russian Federation, Leninskii pr. 31, korp. 4, Moscow, 119071

V. O. Zharkova

Frimkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: kulyukhin@ipc.rssi.ru
Russian Federation, Leninskii pr. 31, korp. 4, Moscow, 119071

S. A. Kulyukhin

Frimkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Author for correspondence.
Email: kulyukhin@ipc.rssi.ru
Russian Federation, Leninskii pr. 31, korp. 4, Moscow, 119071

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2. 1. Modified clay KGPO-23 (1 – KGPO-23-W, 2 – KGPO-23-Carb, 3 – KGPO-23-Az, 4 – KGPO-23-W-Alk, 5 –KGPO-23-Carb-Alk, 6 – KGPO-23-Az-Alk; K – kaolinite, Al2Si2O5(OH)4 [11], Q – quartz [12], F – potassium feldspar, KAlSi3O8 [13], Il – illite, KAl3Si3O10(OH)2 [14], Na-Al – sodium aluminate, Na5AlO4 [19], Na-Si – sodium silicate, Na2Si2O5⋅5H2O [20]).

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3. 2. Modified clay kgpo-28 (1 – kgpo-28-W, 2 – kgpo-28-Carb, 3 –kgpo-28-az, 4 – kgpo-28-W-ALK, 5 –kgpo-28-Carb-ALK, 6 – kgpo-28-az-ALK; K – kaolinite, al2si2o5(Oh)4 [11], Q – quartz [12], F – potassium feldspar, KALSI3O8 [13], IL – Illite, KAL3SI3O10(OH)2 [14], Na-si – aqueous sodium silicate, NA2SIO3⋅5H2O [21], K-si – potassium silicate, K4(H4SI4O12) [23]).

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4. Pain. 3. Modified HBGP clay (1 – HBGP-W, 2 – HBGP-Carb, 3 – HBGP-Az, 4 – HBGP-W-Alk, 5 – HBGP-Carb-Alk, 6 – HBGP-Az-Alk; Q – quartz [12], F – potassium feldspar, KAlSi3O8 [13], Na-Mt – montmorillonite in the Na-form, namgalsio2(OH)⋅H2O [15], CA-Mt –montmorillonite in Ca form, CA0.2(Al, Mg)2SI4O10(oh)2⋅4H2O [16], Il-Mt–Illite-montmorillonite, kal4(Si, Al)8o20(Oh)4⋅xh2o [17], C – calcite, CaCO3 [18], Na-si – aqueous sodium silicate, Na2sio3⋅5H2O [21], Na-SI1 – sodium hydrosilicate, Nahsi2o5 [22], na-Si2 – aqueous sodium silicate, na2si2o5⋅5h2o [20]).

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5. 4. Modified clay DB (1 – DB-W, 2–DB-Carb, 3– DB-Az, 4– DB-W-Alk, 5– DB-Carb-Alk, 6–DB-Az-Alk; Q –quartz [12], Na-Mt – montmorillonite in Na form, NaMgAlSiO2(OH)⋅H2O [15], Ca-Mt –montmorillonite in Ca form, Ca0.2(Al, Mg)2Si4O10(OH)2⋅4H2O [16], Il-Mt – illite-montmorillonite, KAl4(Si, Al)8O20(OH)4⋅xH2O [17], C – calcite, CaCO3 [18], Na-Al – sodium aluminate, Na5AlO4 [19], Na-Si – aqueous sodium silicate, Na2SiO3⋅5H2O [21], Crb – aqueous sodium carbonate Na2CO3⋅H2O [22]).

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6. Fig. 5. Photograph of columns with clay material in the process of saturation with a solution of [UO2(CO3)3]4– and filtration of the solution (a – columns with an unconsolidated air-dry mixture of clay materials; b–d – view of a column with clay material in the process of saturation with a solution of [UO2(CO3)3]4– and filtration of the solution after 45 min (b), 70 h (c), 120 h (d); e – the type of columns at the initial moment of washing with distilled water; mixtures of clay materials (in mass ratio 1 : 1) in columns: 1 – KGPO-28/DB, 2 – KGPO-23/HBGP, 3 – KGPO-28/HBGP, 4 – KGPO-23/DB).

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7. Fig. 6. Change in the height of the water layer above the wet clay material through which the solution [UO2(CO3)3]4–was previously passed. (Mixtures of clay materials (in mass ratio 1 : 1) in columns: 1 – KGPO-28/DB, 2 – KGPO-23/HBGP, 3 – KGPO-28/HBGP, 4 – KGPO-23/DB).

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