Microwave synthesis and luminescent properties of nanosized yttrium vanadate doped with holmium ions

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Abstract

The effect of holmium concentration on the luminescent properties of nanosized HoxY1-xVO4 powders (where x = 0, 0.05, 0.10, 0.15) synthesized by coprecipitation of yttrium vanadate under the influence of microwave radiation was established. The elemental and phase composition, average size of nanopowders (27 ± 2 nm) were determined, the incorporation of Ho3+ ions into the Y3+ ion position was confirmed. The maximum content of holmium ions (10%) was revealed, above which concentration quenching of luminescence was observed. For Ho0.05Y0.95VO4, the luminescence intensity increased by 1.5 times compared to YVO4, while a pronounced band was observed at 550 nm, corresponding to the transition 5F4 /5S2 → 5I8.

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About the authors

E. V. Tomina

Voronezh State University; Voronezh State Forest Engineering University named after G.F. Morozov

Author for correspondence.
Email: tomina-e-v@yandex.ru
Russian Federation, Voronezh; Voronezh

E. V. Popova

Voronezh State University; AO “NIIPM” (Joint-Stock Company “Scientific Research Institute of Semiconductor Engineering”)

Email: tomina-e-v@yandex.ru
Russian Federation, Voronezh; Voronezh

B. V. Sladkopevtsev

Voronezh State University

Email: tomina-e-v@yandex.ru
Russian Federation, Voronezh

Nguen An’ T’en

Ho Chi Minh City Pedagogical University

Email: tomina-e-v@yandex.ru
Russian Federation, Ho Chi Minh City, Vietnam

E. S. Khudyakova

Voronezh State University

Email: tomina-e-v@yandex.ru
Russian Federation, Voronezh

A. A. Solov’eva

Voronezh State University

Email: tomina-e-v@yandex.ru
Russian Federation, Voronezh

A. A. Sinel’nikov

Voronezh State University

Email: tomina-e-v@yandex.ru
Russian Federation, Voronezh

A. V. Doroshenko

Voronezh State University

Email: tomina-e-v@yandex.ru
Russian Federation, Voronezh

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Supplementary files

Supplementary Files
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2. Fig. 1. X-ray diffraction patterns of samples YVO4 (1), Ho0.05Y0.95VO4 (2), Ho0.1Y0.9VO4 (3), Ho0.15Y0.85VO4 (4).

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3. Fig. 2. Energy dispersive spectra of samples YVO4 (a), Ho0.05Y0.95VO4 (b), Ho0.1Y0.9VO4 (c), Ho0.15Y0.85VO4 (d).

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4. Fig. 3. SEM images of YVO4 (a), Ho0.05Y0.95VO4 (b), Ho0.1Y0.9VO4 (c), Ho0.15Y0.85VO4 (d) samples.

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5. Fig. 4. TEM image (a) and particle size distribution histogram (b) of the Ho0.1Y0.9VO4 sample.

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6. Fig. 5. Luminescence spectra of YVO4, Ho0.05Y0.95VO4, Ho0.1Y0.9VO4, Ho0.15Y0.85VO4 samples.

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