Synthesis of Composite Polymer Particles by Seeded Emulsion Polymerization and Formation of Photonic Crystals Based on Them
- 作者: Iakobson O.D.1, Ivan’kova E.M.1, Vaganov G.V.1, Krasnopeeva E.L.1, Shevchenko N.N.1
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隶属关系:
- Institute of Macromolecular Compounds of Russian Academy of Sciences
- 期: 卷 65, 编号 4 (2023)
- 页面: 275-285
- 栏目: СИНТЕЗ
- URL: https://kazanmedjournal.ru/2308-1139/article/view/650881
- DOI: https://doi.org/10.31857/S2308113923700584
- EDN: https://elibrary.ru/QNHAFM
- ID: 650881
如何引用文章
详细
Submicron composite particles with the core/shell structure are synthesized by the seeded emulsion polymerization of a mixture of various acrylates in the presence of a redox initiation system. The diameter, morphology, and surface structure of particles as well as their ability to self-assemble into 3D ordered thin-film structures are studied by scanning electron microscopy, FTIR spectroscopy, thermogravimetry, and dynamic light scattering. It is shown that under the used experimental conditions particles with a shell thickness of 10‒35 nm are synthesized. The effect of shell composition (in particular, the alkyl chain length of acrylate comonomers) on the morphology and structure of the surface layer of the obtained composite particles is traced.
作者简介
O. Iakobson
Institute of Macromolecular Compounds of Russian Academy of Sciences
Email: iakobson.olga@yandex.ru
199004, St. Petersburg, Russia
E. Ivan’kova
Institute of Macromolecular Compounds of Russian Academy of Sciences
Email: natali.shevchenko29@gmail.com
199004, St. Petersburg, Russia
G. Vaganov
Institute of Macromolecular Compounds of Russian Academy of Sciences
Email: natali.shevchenko29@gmail.com
199004, St. Petersburg, Russia
E. Krasnopeeva
Institute of Macromolecular Compounds of Russian Academy of Sciences
Email: natali.shevchenko29@gmail.com
199004, St. Petersburg, Russia
N. Shevchenko
Institute of Macromolecular Compounds of Russian Academy of Sciences
编辑信件的主要联系方式.
Email: natali.shevchenko29@gmail.com
199004, St. Petersburg, Russia
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