Sorption-desorption properties of titanium phosphate towards heavy metal cations

Cover Page

Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription or Fee Access

Abstract

The sorption/desorption behavior of divalent ions (Cu2+, Mn2+,Co2+, Ni2+) on amorphous titanium phosphate is studied.The sorption/desorption equilibrium is shown to be largely determined bythe solvated state of heavy metal cations; selectivity series areconstructed. Regardless of the degree of saturation of the sorbentwith cations of the metals being studied, the desorption degreeexceeds 99.9% in all cases. With multi-stage use of thesorbent, the efficiency of sorption/desorption processes is established to decreasebecause of its dehydration due to hydrolysis of the sorbent,which is 2.6 10–3 mg g–1·h–1. The efficiencyof sorption/desorption of the ions from multicomponent solutions is shown.

About the authors

M. V. Maslova

I. V. Tananaev Institute of Chemistry – Subdivision of the Federal Research Centre «Kola Science Centre of the Russian Academy of Sciences» (ICT KSC RAS)

Email: m.maslova@ksc.ru
Apatity, Murmansk region, Russia

P. E. Evstropova

I. V. Tananaev Institute of Chemistry – Subdivision of the Federal Research Centre «Kola Science Centre of the Russian Academy of Sciences» (ICT KSC RAS)

Email: m.maslova@ksc.ru
Apatity, Murmansk region, Russia

N. V. Mudruk

I. V. Tananaev Institute of Chemistry – Subdivision of the Federal Research Centre «Kola Science Centre of the Russian Academy of Sciences» (ICT KSC RAS)

Email: n.mudruk@ksc.ru
Apatity, Murmansk region, Russia

Yu. P. Semushina

I. V. Tananaev Institute of Chemistry – Subdivision of the Federal Research Centre «Kola Science Centre of the Russian Academy of Sciences» (ICT KSC RAS)

Author for correspondence.
Email: m.maslova@ksc.ru
Apatity, Murmansk region, Russia

References

  1. Barrios-Estrada C., de JesúsRostro-Alanis M., Muñoz-GutiérrezB.D. et al. // Sci. Total Environ. 2018. V. 612.P. 1516. https://doi.org/10.1016/j.scitotenv.2017.09.013
  2. Renge V.C., Khedkar S.V., Pandey Shraddha V. // Sci. Rev. Chem. Commun. 2012. V. 2. № 4.P. 580.
  3. Muya F.N., Ward M., Sunday C.E., et al. // Water Sci. Technol. 2015. V. 73.№ 5. P. wst2015567. https://doi.org/10.2166/wst.2015.567
  4. Fu F., Wang Q. // J. Environ. Manage. 2011. V. 92. № 3. P. 407. https://doi.org/10.1016/j.jenvman.2010.11.011
  5. Trublet M., Maslova M.V., Rusanova D., Antzutkin O.N. //RSC Adv. 2017. V. 7. № 4. P. 1989. https://doi.org/10.1039/C6RA25410A
  6. Maslova M., Ivanenko V., Yanicheva N.,Gerasimova L. // J. Water Process Eng. 2020. V. 35. P. 101233. https://doi.org/10.1016/j.jwpe.2020.101233
  7. TrubletM., Maslova M.V., Rusanova D.,Antzutkin O.N. // Mater.Chem. Phys. 2016. V. 183. P. 467. https://doi.org/10.1016/j.matchemphys.2016.09.002
  8. Aşçı Y.,Nurbaş M., Sağ Açıkel Y. // J. Environ. Manage. 2010.V. 91. № 3. P. 724. https://doi.org/10.1016/j.jenvman.2009.09.036
  9. Temkin M., Pyzhev V. // Acta Physicochim. URSS. 1940. V. 12. P. 217.
  10. Giles C.H., MacEwan T.H., Nakhwa S.N., Smith D. // J. Chem.Soc. 1960. V. 846. P. 3973.
  11. Haynes W.M. Handbook of Chemistryand Physics. 97-th Edition. CRC Press, Taylor & Francis Group,2017. 2643 p.
  12. Шарыгин Л.М., Калягина М.Л., Боровков С.И. //Журн. прикл. химии. 2005. Т. 78. № 2. С. 229.

Supplementary files

Supplementary Files
Action
1. JATS XML

Copyright (c) 2025 Russian Academy of Sciences