Solubility and thermodynamic characteristics of dissolution of tetra-4/3-(Methoxyphenoxy) phthalocyaninates of copper in chloroform

Cover Page

Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription or Fee Access

Abstract

The solubility of tetra-4- and tetra-3-substituted copper phthalocyaninates with ortho-, meta-, or para-phenol moieties in the temperature range 288–318 K is studied. Regularities of dissolution of the compounds in chloroform depending on the position of the substituent located at the periphery of the molecule are discussed. Standard thermodynamic parameters of dissolution of synthesized metal complexes are calculated.

About the authors

A. E. Rassolova

Ivanovo State University of Chemistry and Technology

Email: nastyna_25.05@mail.ru
Ivanovo, 153000 Russia

G. R. Berezina

Ivanovo State University of Chemistry and Technology

Email: nastyna_25.05@mail.ru
Ivanovo, 153000 Russia

V. E. Maizlish

Ivanovo State University of Chemistry and Technology

Author for correspondence.
Email: nastyna_25.05@mail.ru
Ivanovo, 153000 Russia

References

  1. The Porphyrin Handbook / Eds. K.M. Kadish, K.M. Smith, R. Guilard. Academic Press: Elsevier Science (USA), 2003. V. 15. 3925 p.
  2. Phthalocyanines. Properties and Applications / Eds. C.C. Leznoff, A.B.Р. Lever. VCH, Cambrige, 1989. V. 1. P. 341.
  3. Березин Б.Д.Координационные соединения порфиринов и фталоцианина. М.: Наука, 1978. 280 с. [Berezin B.D. Coordination compounds of porphyrins and phthalocyanine. M.: Nauka, 1978. 280 p.]
  4. Данилова Е.А., Галанин Н.Е., Исляйкин М.К. и др. // Изв. вузов. Химия и хим. технология. 2023. Т. 66. Вып. 7. С. 111. [Danilova E.A., Galanin N.E., Islyaykin M.K., et al. // ChemChemTech [Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol.]. 2023. V. 66. I. 7. P. 111.]
  5. Hamad O.A., Kareem R.O., Omer P.K. // J. of Chemical Reviews. 2024. V. 6. № 1. P. 39.
  6. Шапошников Г.П., Кулинич В.П., Майзлиш В.Е.Модифицированные фталоцианины и их структурные аналоги / Под ред. О.И. Койфмана. М.: КРАСАНД, 2012. 480 с.
  7. Li D., Cai S., Wang P., et al. //Advanced Healthcare Materials. 2023. V. 12. № 22. P. 2300263.
  8. Santos K.L.M., Barros R.M., da Silva Lima D.P., et al. // Photodiagnosis and Photodynamic Therapy.2020. V. 32. P. 102032.
  9. Смирнова А.И., Кулев В.А, Рассолова А.Е. и др. // Жидк. крист. и и практич. использование. 2022. Т. 22. № 4. C. 37. [Smimova A.I., Kulev V.A., Rassolova A.E., et al. // Russ. Liq. Cryst. and their Appl. 2022. V. 22. № 4. P. 37.]
  10. Hiromu Nakamura, Kouki Sugiyama, Kazuchika Ohta, Mikio Yasutake // J. Materials Chemistry C. 2017. V. 5. P. 7297.
  11. Березина Г.Р., Борисов А.В., Майзлиш В.Е., Шапошников Г.П. //Координац. химия. 2006. Т. 32.№ 8. С. 600. [Berezina G.R., Borisov A.V., Maizlish V.E., Shaposhnikov G.P. // Coordination chemistry. 2006. V. 32. № 8. Р. 575.] doi: 10.1134/S1070328406080082.
  12. Березина Г.Р. // Журн. физ. химии. 2021. Т. 95. № 6. С. 890. [Berezina G.R. //J. Phys. Chem. 2021. V. 95. № 6. P. 1152.] doi: 10.1134/S0036024421060030.
  13. Erzunov D., Rassolova A., Botnar A., et al. // Dyes and Pigments. 2023. V. 219. P. 111600.
  14. Васильев В.П.Термодинамические свойства растворов электролитов. М.: Высш. школа, 1982. С. 320. [Vasil’ev V.P.Thermodynamic properties of electrolyte solutions. M.: Higher school, 1982. P. 320.]
  15. Оcипов Ю.М., Исляйкин М.К., Шапошников Г.П, и др.// Изв. вузов. Химия и хим. технология. 1988. Т. 31. Вып. 3. C. 31. [Osipov Yu.M., Islyaykin M.K., Shaposhnikov G.P., et al. // ChemChemTech [Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol.]. 1988. V. 31. I. 3. P. 31.
  16. Березин Б.Д., Койфман О.И., Никитина Г.Е. // Журн. физ. химии. 1980. Т. 54. № 2. С. 2481. [Berezin B.D., Koifman O.I., Nikitina G.E. // J. Phys. Chem. 1980. V. 54. № 2. P. 2481.]

Supplementary files

Supplementary Files
Action
1. JATS XML
Download

Copyright (c) 2025 Russian Academy of Sciences